NMR experiments offered

The NMR facility routinely performs standard solution-state NMR experiments:

One-dimensional NMR

¹H, ¹³C, DEPT

DOSY-NMR

Temperature series -80 to +80 °C

Heteronuclei: ⁷Li, ¹¹B, ¹⁹F, ²⁹Si, ³¹P

Two-dimensional NMR

NOESY, TOCSY, HMQC, HSQC, HMBC (¹³C, ¹⁵N, ³¹P)

 

If your project would benefit from customized NMR experiments, please get in touch with the NMR facility team.

 

For inspiration, here is a list of successful projects conducted in collaboration with the facility.

 

    

Aryl Radicals Generated from Aryl Pinacol Boronates Modify Peptides and Proteins.

Chen, Wu, Holzinger, Götz, Didier, Schütz, Schneider, Kielkowski. Eur. J. Org. Chem. (2024).

A systematic QM/MM study for predicting 31P NMR chemical shifts of adenosine nucleotides in solution and stages of ATP hydrolysis in a protein environment

Szanto,  Dietschreit, Shein,  Schuetz, Ochsenfeld. Eur. J. Org. Chem. 2024. Journal of Chemical Theory and Computation (2024).

Quantification of the Electrophilicities of Diazoalkanes: Kinetics and Mechanism of Azo Couplings with Enamines and Sulfonium Ylides
Li, Mayer, Stephenson, Mayer, Ofial, Mayr. Chem. Eur. J. 2022.

An Overlooked Pathway in 1,3-Dipolar Cycloadditions of Diazoalkanes with Enamines
Li, Mayer, Stephenson, Ofial, Mayer, Mayr. Angew. Chem. Int. Ed. 2022.

Isoxazole Nucleosides as Building Blocks for a Plausible Proto-RNA
Xu, Crisp, Schinkel, Dubini, Hübner, Becker, Schelter, Rovó, Carell, Angew. Chem. Int. Ed. 2022.

F. Xu, A. Crisp, T. Schinkel, R. C. A. Dubini, S. Hübner, S. Becker, F. Schelter, P. Rovó, T. Carell, Angew. Chem. Int. Ed. 2022, 61, e202211945; Angew. Chem. 2022, 134, e202211945.

Rational Design of Covalent Cobaloxime–Covalent Organic Framework Hybrids for Enhanced Photocatalytic Hydrogen Evolution
Gottschling, Savasci, Vignolo-González, Schmidt, Mauker, Banerjee, Rovó, Ochsenfeld, Lotsch. J. Am. Chem. Soc. 2020

Sunlight-powered kHz rotation of a hemithioindigo-based molecular motor
Guentner, Schildhauer, Thumser, Mayer, Stephenson, Mayer, Dube. Nature communications 2015.