NMR experiments offered

The NMR facility routinely performs standard solution-state NMR experiments:

One-dimensional NMR

¹H, ¹³C, DEPT

DOSY-NMR

Temperature series -80 to +80 °C

Heteronuclei: ⁷Li, ¹¹B, ¹⁹F, ²⁹Si, ³¹P

Two-dimensional NMR

NOESY, TOCSY, HMQC, HSQC, HMBC (¹³C, ¹⁵N, ³¹P)

 

If your project would benefit from customized NMR experiments, please get in touch with the NMR facility team.

 

For inspiration, here is a list of successful projects conducted in collaboration with the facility.

Quantification of the Electrophilicities of Diazoalkanes: Kinetics and Mechanism of Azo Couplings with Enamines and Sulfonium Ylides
Li, Mayer, Stephenson, Mayer, Ofial, Mayr. Chem. Eur. J. 2022.

An Overlooked Pathway in 1,3-Dipolar Cycloadditions of Diazoalkanes with Enamines
Li, Mayer, Stephenson, Ofial, Mayer, Mayr. Angew. Chem. Int. Ed. 2022.

Isoxazole Nucleosides as Building Blocks for a Plausible Proto-RNA
Xu, Crisp, Schinkel, Dubini, Hübner, Becker, Schelter, Rovó, Carell, Angew. Chem. Int. Ed. 2022.

F. Xu, A. Crisp, T. Schinkel, R. C. A. Dubini, S. Hübner, S. Becker, F. Schelter, P. Rovó, T. Carell, Angew. Chem. Int. Ed. 2022, 61, e202211945; Angew. Chem. 2022, 134, e202211945.

Formation of Cisplatin Adducts with the Epigenetically Relevant Nucleobase 5-Methylcytosine
Menke, Dubini, Mayer,  Rovó,  Daumann.  Eur. J. Inorg. Chem. 2021.

Rational Design of Covalent Cobaloxime–Covalent Organic Framework Hybrids for Enhanced Photocatalytic Hydrogen Evolution
Gottschling, Savasci, Vignolo-González, Schmidt, Mauker, Banerjee, Rovó, Ochsenfeld, Lotsch. J. Am. Chem. Soc. 2020

Sunlight-powered kHz rotation of a hemithioindigo-based molecular motor
Guentner, Schildhauer, Thumser, Mayer, Stephenson, Mayer, Dube. Nature communications 2015.